Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 24, Issue 19, Pages 11573-11584Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cp00166g
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Funding
- Hong Kong Quantum AI Lab Ltd.
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Recent mean-field theories predict spontaneous surface charge separation in room-temperature ionic liquid electric double-layer capacitors without applied potential. In this study, a coarse-grained molecular model is constructed to directly simulate the behavior of the ionic liquid, revealing the importance of image charge interactions and enhanced in-plane ordering on electrodes, which are not considered by mean-field theories.
Recent mean-field theories predict that room-temperature ionic liquid (RTIL) electric double-layer capacitors (EDLCs) undergo a spontaneous surface charge separation (SSCS) with no applied potential. In this study, we construct a coarse-grained molecular model that corresponds to the mean-field models to directly simulate the behavior of RTILs without invoking mean-field approximations. In addition to observing the SSCS transition, we highlight the importance of the image charge interactions and explore the enhanced in-plane ordering on the electrodes, two effects not accounted for by the mean-field theories. By calculating and comparing the differential capacitance for RTILs confined between perfectly conducting and non-metal electrodes, we show that the image charge interactions drastically improve the energy storage properties of RTIL EDLCs.
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