Nitrogen-doped 3D hollow carbon spheres for efficient selective oxidation of C-H bonds under mild conditions

Heteroatom-doped carbon-based materials are considered to be efficient metal-free catalysts for diverse organic synthetic reactions. However, compared with metal-based catalysts, there are still gaps in the catalytic performance of metal-free catalysts in the selective catalytic oxidation of C-H bonds. Herein, nitrogen-doped 3D hollow carbon spheres (N-HCSs) were prepared by the chemical vapor deposition (CVD) method. And the effects of deposition temperature, nitrogen content and pore structure on the catalytic performance are systematically investigated. For the model oxidation reaction of ethylbenzene, the obtained catalyst shows 98.4% conversion of ethylbenzene and 99.5% selectivity of acetophenone at 50 degrees C. The abundant mesopores and modest graphite nitrogen content are confirmed to be beneficial for improving their catalytic activity in the selective oxidation of C-H bonds.

Automated summary

Heteroatom-doped carbon-based materials, such as nitrogen-doped 3D hollow carbon spheres (N-HCSs), show great potential as metal-free catalysts for selective oxidation of C-H bonds. The catalytic performance of N-HCSs is influenced by deposition temperature, nitrogen content, and pore structure. Higher mesopore abundance and moderate graphite nitrogen content enhance the catalytic activity of N-HCSs.