4.6 Article

Thermoelectric performance enhancement of eco-friendly Cu2Se through incorporating CB4

Journal

RSC ADVANCES
Volume 12, Issue 22, Pages 14112-14118

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ra01546c

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Funding

  1. Projection of State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology [20FKSY23]

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Cu2Se + x wt% CB4 composites were prepared by a hydrothermal method and hot-pressing technique. The electrical properties testing showed high power factor and suppressed thermal conductivity. CB4 could effectively improve the thermoelectric performance of Cu2Se.
We have prepared Cu2Se + x wt% CB4 composites with x = 0, 0.1, 0.3, 0.5, and 0.7 by a hydrothermal method and hot-pressing technique. The structural and compositional analysis indicates that pure phase Cu2Se powders were synthesized and the densified layered bulk samples were obtained. Electrical properties testing showed that the sample with x = 0.5 has the high power factor of 0.886 mW m(-1) K-2 due to its high Seebeck coefficient. Meanwhile, the thermal conductivity was suppressed to 0.6 W m(-1) K-1 at 773 K. As a result, the final optimized ZT value of 1.46 at 773 K was achieved. These results suggest that CB4 could be an alternative inclusion to improve effectively the thermoelectric performance of Cu2Se.

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