4.7 Article

BINOL blocks as accessible triplet state modulators in BODIPY dyes

Journal

CHEMICAL COMMUNICATIONS
Volume 58, Issue 44, Pages 6385-6388

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00991a

Keywords

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Funding

  1. MICINN [PID2020-114755GB-C32, PID2020-114755GB-C-33, PID2020-114347RB-C32, MARSA21/71]
  2. Royal Society [URF\R\191002]
  3. UE [H2020-MSCA-ITN-859752, HEL4CHIROLED]
  4. BBSRC [BB/S017615/1]
  5. Basque Government [IT1639-22]
  6. CM/UCM
  7. BBSRC [BB/S017615/1] Funding Source: UKRI

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The development from BINOL moieties to O-BODIPY dyes paves the way for photonics applications based on triplet excited states of BODIPY dyes.
BINOL moieties of different electronic demand are useful blocks for enabling the photo-production and modulation of triplet excited states in readily-accesible BINOL-based O-BODIPY dyes from standard F-BODIPY precursors. The rapid and rational development of smarter triplet-enabling BODIPY dyes on the basis of this strategy (e.g., TADF biomarker 4a or room temperature phosphor 4g) paves the way for advancing photonic applications based on organic triplet photosensitizers.

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