Journal
CHEMICAL SCIENCE
Volume 13, Issue 21, Pages 6366-6372Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2sc01593e
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Funding
- National Key RAMP
- D Program of China [2019YFA0308000]
- Natural Science Foundation of China [22173048]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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Using bismuth nanosheets and Bi-N-C SAC as model catalysts, this study computationally reveals the correlation between the selectivity of M-N-C SACs and the CO2 adsorption mode, providing guidance for the development of high-performance CO2RR catalysts.
Formate and CO are competing products in the two-electron CO2 reduction reaction (2e CO2RR), and they are produced via *OCHO and *COOH intermediates, respectively. However, the factors governing CO/formate selectivity remain elusive, especially for metal-carbon-nitrogen (M-N-C) single-atom catalysts (SACs), most of which produce CO as their main product. Herein, we show computationally that the selectivity of M-N-C SACs is intrinsically associated with the CO2 adsorption mode by using bismuth (Bi) nanosheets and the Bi-N-C SAC as model catalysts. According to our results, the Bi-N-C SAC exhibits a strong thermodynamic preference toward *OCHO, but under working potentials, CO2 is preferentially chemisorbed first due to a charge accumulation effect, and subsequent protonation of chemisorbed CO2 to *COOH is kinetically much more favorable than formation of *OCHO. Consequently, the Bi-N-C SAC preferentially produces CO rather than formate. In contrast, the physisorption preference of CO2 on Bi nanosheets contributes to high formate selectivity. Remarkably, this CO2 adsorption-based mechanism also applies to other typical M-N-C SACs. This work not only resolves a long-standing puzzle in M-N-C SACs, but also presents simple, solid criteria (i.e., CO2 adsorption modes) for indicating CO/formate selectivity, which help strategic development of high-performance CO2RR catalysts.
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