Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 9, Issue 12, Pages 3354-3359Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qo00617k
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Funding
- National Natural Science Foundation of China [21871087]
- Open Research Fund of Key Laboratory of Polar Materials and Devices, Ministry of Education
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An atom-economical transition-metal-free protocol for the stereoselective synthesis of conjugated trienes has been developed via base promoted C-C sigma-bond cleavage reactions of allyl carbonyl compounds. This methodology efficiently constructs a broad range of conjugated trienes with the advantages of mild reaction conditions, low cost, and operational simplicity.
An atom-economical transition-metal-free protocol for the stereoselective synthesis of conjugated trienes has been developed. These transformations were realized through base promoted C-C sigma-bond cleavage reactions of allyl carbonyl compounds. This methodology efficiently constructs a broad range of conjugated trienes with the advantages of mild reaction conditions, low cost and operational simplicity.
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