Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 46, Pages 6630-6633Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc02089k
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Funding
- SERB (DST), India [CRG/2021/001951]
- IISER Mohali
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Formazan ligands have long been investigated as redox-noninnocent backbones, but their catalytic efficiency governed by redox noninnocence remains elusive. In this study, we report an iron-formazanate molecule that can efficiently prepare alpha-keto amides through a tightly regulated reductive cleavage of the substrate molecule by the electron donation from the formazanate, in a reversible manner.
The formazan ligands have been investigated as redox-noninnocent backbones for a long time. Despite their well-established behaviour as redox reservoirs, the demonstration of catalytic efficiency governed by redox noninnocence remains elusive. We report an iron-formazanate molecule for efficiently preparing alpha-keto amides, where a crucial reductive cleavage of the substrate molecule is tightly regulated by the electron donation from the formazanate, in a reversible manner.
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