Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 47, Pages 6705-6708Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc02054h
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Funding
- National Natural Science Foundation of China [22071039, 22101068]
- Natural Science Foundation of Zhejiang Province [LQ21B020007]
- Scientific Research Fund of Zhejiang Provincial Education Department [Y202147386]
- Shanxi Supercomputing Centre of China
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In this study, the synthesis, structural characterization, and density functional theory (DFT) calculations of trinuclear anionic gold clusters ligated by dialkylsilylene and dialkylgermylene were reported.
While the chemistry of gold clusters has been developed rapidly, the knowledge of trinuclear gold clusters with low-valent gold remains scarce. Herein, we report the synthesis, structural characterization, and density functional theory (DFT) calculations of trinuclear anionic gold clusters 3a and 3b ligated by dialkylsilylene (1a) and dialkylgermylene (1b), respectively.
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