4.6 Article

Gate-Controlled NiO/Graphene/4H-SiC Double Schottky Barrier Heterojunction Based on a Metal-Oxide-Semiconductor Structure for Dual-Mode and Wide Range Ultraviolet Detection

Journal

ACS APPLIED ELECTRONIC MATERIALS
Volume 4, Issue 4, Pages 1807-1814

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsaelm.2c00056

Keywords

graphene; NiO; SiC; dual-mode UV photodetector; wide spectrum response

Funding

  1. National Natural Science Foundation of China [12074182]
  2. Collaborative Innovation Center of Solid-State Lighting and Energy-saving Electronics
  3. Open Fund of the State Key Laboratory on Integrated Optoelectronics [IOSKL2017KF03]

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This study presents a double Schottky barrier junction (SBJ) device for ultraviolet detection. By modulating the gate voltage, the device can operate in both photoconductive and Schottky photodiode modes. The device exhibits high responsivity and gain despite low light intensity, and has a wide UV response range.
Based on a metal-oxide-semiconductor (MOS) structure, a double Schottky barrier junction (SBJ) made of NiO/graphene/4H-SiC is built and employed in ultraviolet (UV) detection. The hole concentration of NiO can be modulated as depleted or accumulated states with gate voltages, which allows the device to work in dual-mode when used as a photodetector. In this work, a negative gate bias causes the device to operate as a photoconductive detector with gain due to the negligible Schottky barrier, whereas a zero or positive gate bias makes it work as a Schottky photodiode. The device has a high responsivity of 103.3 A/W and a gain of 490.8 despite the low light intensity (261 nm laser @ 30.19 mu W/cm(2)) at V-DS = 5 V and V-GS = -3 V. The NiO layer and SiC substrate both serve as UV absorption materials and produce photogenerated carriers, and the device has a wide UV response range from 240 to 400 nm with a gain of 80.34 when V-DS = -3 V and V-GS = 0 V at 240 nm. The above findings suggest that this MOS-based NiO/graphene/4H-SiC double SBJ has a great prospect in practical UV detection.

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