4.6 Article

FeCl3-mediated selenylative benzannulation of aryl alkynones to 3-selenyl β-naphthols

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 20, Issue 23, Pages 4765-4772

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ob00321j

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Funding

  1. Science and Engineering Research Board (SERB), Department of Science and Technology, New Delhi [EMR/2016/006253]
  2. Council of Scientific and Industrial Research (CSIR), New Delhi [IICT/pubs./2022/061]

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An efficient selenylative cyclization of aryl-alkynones with diselenides in the presence of iron(iii)chloride at room temperature to prepare 3-seleno-2-naphthols in good yields has been described. Furthermore, the resulting products were transformed into selenyl-naphthofuran and selenyl-1,2-naphthoquinone derivatives.
An efficient selenylative cyclization of aryl-alkynones with diselenides in the presence of iron(iii)chloride at room temperature to prepare 3-seleno-2-naphthols in good yields has been described. Furthermore, the resulting products were transformed into selenyl-naphthofuran and selenyl-1,2-naphthoquinone derivatives.

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