4.4 Article

Keeping the name clean: [2+2] photocycloaddition

Journal

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
Volume 21, Issue 8, Pages 1333-1340

Publisher

SPRINGERNATURE
DOI: 10.1007/s43630-022-00239-7

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Funding

  1. US National Science foundation [CHE-1955524, CHE-1807729]
  2. German Science Foundation
  3. European Research Council

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This perspective clarifies the terminology used for different [2 +2] photocycloaddition processes and aims to establish a standard to assist researchers in using the correct terminologies.
Crossed [2 + 2] photocycloaddition is a specific case of intramolecular photocycloaddition reaction. Recently, the term crossed [2 +2] photocycloaddition is interchangeably used to represent intermolecular [2 +2] photocycloaddition reactions of two dissimilar double bonds/alkenes. To avoid confusion and to help researchers use the correct terminologies, this perspective clarifies the terminology used for different [2 +2] photocycloaddition processes based on prior literature with the hope of establishing a standard for addressing the diverse set of photocycloaddition reactions that will be helpful to the chemical community. [GRAPHICS] .

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