4.6 Article

A novel three-position molecular switch based on the transformations of a cyano-substituted pyrrol-2-one derivative

Journal

NEW JOURNAL OF CHEMISTRY
Volume 46, Issue 23, Pages 11030-11034

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2nj01658c

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Funding

  1. Russian Science Foundation [21-73-10303]
  2. Russian Science Foundation [21-73-10303] Funding Source: Russian Science Foundation

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This study demonstrates the possibility of creating the first representative of a novel group of molecular switches that are sensitive to solvent, acid-base reagents, and temperature changes, based on the directionally synthesized 5-phenyl-1,3-dihydro-2H-pyrrol-2-one containing a buta-1,3-diene-1,1,3-tricarbonitrile acceptor. The obtained result reveals a new research direction in the field of multicolor reversibly tunable molecular systems sensitive to several factors.
The possibility of creating the first representative of a novel group of molecular switches sensitive to the solvent, to the action of acid-base reagents and to temperature changes has been shown based on the directionally synthesized 5-phenyl-1,3-dihydro-2H-pyrrol-2-one containing a buta-1,3-diene-1,1,3-tricarbonitrile acceptor. The obtained result reveals a new branch of research in the field of multicolor reversibly tunable molecular systems sensitive to several factors.

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