Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 52, Pages 7257-7260Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc02489f
Keywords
-
Categories
Funding
- JSPS KAKENHI Grants [JP22K05135]
- JSPS
Ask authors/readers for more resources
The ortho-selective benzylic C(sp(3))-H alkenylation of 2-methyl tertiary anilines with internal alkynes has been achieved for the first time by using a half-sandwich scandium catalyst. This protocol provides a straightforward route for the synthesis of a new family of 2-allylaniline derivatives, featuring broad substrate scope, 100% atom-efficiency, high yields, and high chemo-, regio-, and stereoselectivity.
The ortho-selective benzylic C(sp(3))-H alkenylation of 2-methyl tertiary anilines with internal alkynes has been achieved for the first time by using a half-sandwich scandium catalyst. This protocol provides a straightforward route for the synthesis of a new family of 2-allylaniline derivatives, featuring broad substrate scope, 100% atom-efficiency, high yields, and high chemo-, regio-, and stereoselectivity.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
