Journal
RSC ADVANCES
Volume 12, Issue 26, Pages 16772-16778Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ra02595g
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Funding
- National Natural Science Foundation of China [22161017, 22161016]
- Start-up Research Foundation of Hainan University (KYQD) [KYQD(ZR)1852, KYQD(ZR)22034]
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Curcumin derivatives modified with tetraphenylethylene (TPE) can be used as on-off fluorescence probes for detecting Cu2+ ions in aqueous solution. This TPE-modified strategy improves the detection capability of curcumin probe and provides a feasible way to obtain other probes with aggregation-caused quenching (ACQ) characteristics.
Curcuminoids have been extensively investigated as metal ion probes, but the intrinsic aggregationcaused-quenching (ACQ) characteristic of curcumin would hinder their applications in aqueous solution. Fortunately, tetraphenylethylene (TPE) could endow the compounds with aggregation-induced emission (AlE)/aggregation-induced enhanced emission (AIEE) characteristics to eliminate the ACQ effect. According to this strategy, a series of TPE-modified curcumin derivatives L1-4 were prepared and studied for their AIEE properties. Among the four TPE-curcumin analogues, only L1 particles have been successfully used as an on-off fluorescence probe for detecting Cu2+ in aqueous solution. The fluorescence titration experiment determined its detection limit of 1.49 x 10(-7) mol L-1, and the binding ratio between L1 and Cu2+ was estimated as 2 : 1, which was in agreement with the results of high resolution mass spectrum and Job's plot. In addition, the binding constant was evaluated as 6.77 x 10(2) M-1 using a Benesi-Hildebrand plot. Finally, the obtained L1-based indicator paper showed significant fluorescence response to Cu2+ aqueous solution. This TPE-modified strategy improves the detection capability of curcumin probe in aqueous solution and provides a feasible way to obtain other probes with ACQ characteristics.
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