Journal
JOURNAL OF CLEANER PRODUCTION
Volume 359, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2022.132107
Keywords
Polyurethane foam; Open-cell foam; Bio-polyol; Used cooking oil; Thermal insulation
Categories
Funding
- National Centre for Research and Development in Poland [LIDER/28/0167/L-8/16/NCBR/2017]
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This article discusses the potential of using used cooking oil as a feedstock for producing open-cell polyurethane foam. The study focuses on the effects of bio-polyol properties on the properties of the final foam, and the key step in the synthesis of bio-polyols. The results show that the foams produced using used cooking oil-based polyols have comparable properties to commercial products.
Used cooking oil is a widely available and inexpensive waste with a high application potential as a feedstock for the bio-based polyurethane production. Usually, bio-polyols from vegetable oils have higher viscosity and lower hydroxyl values compared to commercial petrochemical polyols, which limits their usefulness. This article reports on the development of open-cell polyurethane foam systems wherein 100% of the polyol components were bio-polyols obtained from used cooking oil. What is particularly considered is the effect of bio-polyol properties (molecular weight, viscosity and hydroxyl value) on the properties of the final open-cell polyurethane systems apparent density, thermal conductivity coefficient, content of closed cells, mechanical strength, brittleness and short-term water absorption. It was found that the key step in the synthesis of bio-polyols designed for open-cell polyurethane foams is the epoxidation reaction. The epoxy value has a significant effect on the occurrence of side reactions (mainly oligomerization) during the oxirane ring-opening process determining the properties of biopolyols. The resulting open-cell foams were characterized by apparent densities from 12.4 to 13.3 kg/m3, thermal conductivity coefficients from 36.6 to 38.2 mW/m center dot K, and closed cell contents below 10%, which makes them comparable to commercial products. The results demonstrate that used cooking oil-based polyols can provide an alternative starting material for open-cell polyurethane foam production.
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