4.7 Article

Study of highly stable electrochemiluminescence from [Ru(bpy)3]2+/dicyclohexylamine and its application in visualizing sebaceous fingerprint

Journal

CHEMICAL COMMUNICATIONS
Volume 58, Issue 52, Pages 7305-7308

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc01929a

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Funding

  1. DST-INSPIRE SRF fellowship [IF180116]
  2. SERB [EMR/2017/004 4 49]

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This study reports for the first time a novel and highly stable visual electrochemiluminescence emission system at physiological pH conditions, with a high quantum efficiency. Furthermore, a simple and rapid smartphone-based non-destructive mode for sebaceous fingerprint electrochemiluminescence mapping has been successfully demonstrated.
For the first time, we report a novel and highly stable visual electrochemiluminescence emission from the [Ru(bpy)(3)](2+)/dicyclohexylamine system at physiological pH conditions, with a quantum efficiency (phi(ECL)) of 95.5%. Furthermore, we have successfully demonstrated the simple and rapid smartphone-based ECL mapping of sebaceous fingerprints via a non-destructive mode.

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