A chiral 3D silver(i)-benzenedithiolate coordination polymer exhibiting photoemission and non-linear optical response

A new tridimensional metal-organic chalcogenolate, made of a 1,3-benzenedithiolate bridging ligand and Ag(i), [Ag-2(1,3-BDT)](n), is reported. This coordination polymer has good thermal stability in air and displays both photoluminescence properties and a second harmonic generation response.

Automated summary

A new tridimensional metal-organic chalcogenolate, [Ag-2(1,3-BDT)](n), containing a 1,3-benzenedithiolate bridging ligand and Ag(i), is reported. This coordination polymer exhibits good thermal stability in air and shows photoluminescence properties as well as a second harmonic generation response.