4.6 Article

Mesh Bias Controlled Synthesis of TiO2 and Al0.74Ti0.26O3 Thin Films by Mist Chemical Vapor Deposition and Applications as Gate Dielectric Layers for Field-Effect Transistors

Journal

ACS APPLIED ELECTRONIC MATERIALS
Volume 4, Issue 5, Pages 2516-2524

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsaelm.2c00286

Keywords

titanium oxide; aluminum titanium oxide; mist chemical vapor deposition; field-effect transistors; size distribution of mist precursor

Funding

  1. JSPS KAKENHI [JP20K05318]

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The effect of applying a mesh bias during the synthesis of a-TiO2 thin films via mist-CVD was investigated. It was found that the negative bias promoted the generation of fine mist particles and a dense network structure, resulting in smooth and high-quality a-TiO2 films.
The effect of applying a mesh bias during the syntheses of amorphous titanium oxide (a-TiO2) thin films via mist chemical vapor deposition (mist-CVD) was investigated. When a negative bias is applied to the upstream electrode, some of the large mist particles are captured by the mesh electrode, promoting the generation of fine mist particles and increases the number density, resulting in a smooth and dense a-TiO2 network. As a result, the rate of deposition of the a-TiO2 thin films and the surface roughness decreased. The dielectric constant of the a-TiO2 film also increases from 48 to 57.5. These findings suggest that in the synthesis of a-TiO2 films by mist-CVD is promising for promoting the generation of dense a-TiO2 networks and improving the junction properties at the a-TiO2/c-Si interface. Additionally, the effect of applying a mesh bias in the synthesis of amorphous aluminum titanium oxide (a-Al0.74Ti0.26O3) thin alloy films was studied.

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