4.7 Article

Phytate-coordinated nickel foam with enriched NiOOH intermediates for 5-hydroxymethylfurfural electrooxidation

Journal

CHEMICAL COMMUNICATIONS
Volume 58, Issue 55, Pages 7626-7629

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc02182j

Keywords

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Funding

  1. National Natural Science Foundation of Shaanxi Province, China [2020JM-039, 2019JQ486, 2022JQ-433]
  2. Fundamental Research Funds for the Central Universities [D5000210601]

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This study demonstrates the enrichment of NiOOH intermediates on phytate-coordinated Ni foam through a phytate coordination-induced method, resulting in enhanced electro-oxidation performance for 5-hydroxymethylfurfural.
Manipulating the surface reconstruction of Ni-based catalysts to form NiOOH intermediates is crucial for electrooxidation. Herein, we report a phytate coordination-induced enrichment of NiOOH on phytate-coordinated Ni foam, which exhibited high catalytic performance for 5-hydroxymethylfurfural electro-oxidation. The HMF oxidation rate of 0.76 mmol h(-1) outperformed the majority of Ni-based catalysts.

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