Journal
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
Volume 92, Issue 5, Pages 801-805Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070363222050085
Keywords
isocyanates; carbamoyl azides; 1-substituted tetrazol-5-ones; sodium azide; zinc(II) chloride
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Carbamoyl azides can be formed by the reaction of isocyanates with NaN3 in the presence of ZnCl2 in organic solvents. The formation of carbamoyl azides is completed within 5-10 minutes at room temperature, preventing the release of hydrogen azide. The obtained carbamoyl azides can be used for the synthesis of 1-substituted tetrazol-5-ones without isolation.
Isocyanates readily reacts with NaN3 in the presence of ZnCl2 in organic solvents to form the corresponding carbamoyl azides. The formation of carbamoyl azides completed in 5-10 min at room temperature, which prevent the risk of release of hydrogen azide. The obtained carbamoyl azides without isolation can be used for the preparation of 1-substituted tetrazol-5-ones.
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