Journal
NEW JOURNAL OF CHEMISTRY
Volume 46, Issue 27, Pages 12905-12909Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2nj02462d
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Funding
- SERB-DST, New Delhi [CRG/2020/003634]
- SERB-DST
- CSIR-India
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This paper describes a catalyst-free hydrosulfonation reaction for densely functionalized alkenes. Alkenes with a hydroxy-oxindole moiety were reacted with arylsulfinic acids in green media, resulting in sulfones with yields of 72-86% and excellent diastereoselectivity.
An atom-economical hydrosulfonation of densely functionalized alkenes under catalyst-free conditions is described. Alkenes possessing a hydroxy-oxindole moiety underwent hydrosulfonation on treatment with arylsulfinic acids in green media to afford the resulting sulfones in 72-86% yields with excellent diastereoselectivity.
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