Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 62, Pages 8618-8621Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc03066g
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Funding
- Agence Nationale de la Recherche [ANR-17-CE07-0014-01]
- Agence Nationale de la Recherche (ANR) [ANR-17-CE07-0014] Funding Source: Agence Nationale de la Recherche (ANR)
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This study investigates the wrapping of an aromatic oligoamide helix around an active ester-containing [2]rotaxane, which enforces the sliding and sequestration of the surrounding macrocycle around a part of the axle without any formal affinity. The foldamer-mediated compartmentalization of the [2]rotaxane shuttle was subsequently used to prepare an improbable rotaxane.
The wrapping of an aromatic oligoamide helix around an active ester-containing [2]rotaxane enforced the sliding and the sequestration of the surrounding macrocycle around a part of the axle for which it has no formal affinity. The foldamer-mediated compartmentalization of the [2]rotaxane shuttle was subsequently used to prepare an improbable rotaxane.
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