Journal
DALTON TRANSACTIONS
Volume 51, Issue 27, Pages 10357-10360Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt00458e
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Funding
- DFG [SFB/TRR 88]
- state of Baden-Wurttemberg through bwHPC
- German Research Foundation (DFG) [INST 40/575-1 FUGG]
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The versatile metalloligand was converted into early-late heterotetrametallic complexes, which showed photoluminescence with either remarkably different or similar features compared to related solely coinage metal containing acetylide amidinate complexes.
The versatile metalloligand [{HC CC(NDipp)(2)}(2)Au-2] (dipp = 2,6-diisopropylphenyl) was converted into early-late heterotetrametallic complexes [{ClCp2MC CC(NDipp)(2)}(2)Au-2] (M = Ti, Zr). These compounds show photoluminescence with either remarkably different (Ti) or similar (Zr) features as compared to related solely coinage metal containing acetylide amidinate complexes.
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