Journal
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 58, Issue 5, Pages 720-723Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070428022050128
Keywords
copper-platinum bimetallic catalyst; hydrogenation; 3-methylbut-3-en-1-yl acetate; isoprenol
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Funding
- Ministry of Science and Higher Education of the Russian Federation [075-15-2021-978]
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The catalytic synthesis of isoprenol by hydrogenation of 3-methylbut-3-en-1-yl acetate on heterogeneous bimetallic Cu-Pt catalysts was successfully carried out for the first time. The best selectivity of isoprenol (76%) and full ester conversion were achieved using the 5%Cu-1%Pt/SiO2 catalyst within 6 hours.
The catalytic synthesis of isoprenol by hydrogenation of 3-methylbut-3-en-1-yl acetate on heterogeneous bimetallic Cu-Pt catalysts was carried out for the first time. The best selectivity of isoprenol (76%) was obtained on the 5%Cu-1%Pt/SiO2 catalyst with a full ester conversion in 6 h of the reaction.
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