4.7 Article

Manganese-catalysed hydroperoxidation of carbon-carbon double bonds using molecular oxygen present in air and hydroxylamine under ambient conditions

Journal

ORGANIC CHEMISTRY FRONTIERS
Volume 3, Issue 11, Pages 1420-1424

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6qo00318d

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Funding

  1. JSPS [15K18837]
  2. Kitasato University
  3. Grants-in-Aid for Scientific Research [15K18837] Funding Source: KAKEN

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A highly efficient manganese-catalysed hydroperoxidation of carbon-carbon double bonds of enynes as well as styrene derivatives using N-hydroxyphthalimide, N-hydroxybenzotriazole or N-hydroxysuccinimide was developed. This reaction proceeded at room temperature through the direct incorporation of molecular oxygen present in air. The required catalytic loading of manganese(III) acetylacetonate is extremely low (generally 0.02-0.5 mol%, and a minimum of 0.001 mol%).

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