Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 3, Issue 10, Pages 1295-1298Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6qo00255b
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The low-valent Fe-complex Bu4N[Fe(CO)(3)(NO)] (TBA[Fe]) catalyzes the reductive cleavage of N-O-bonds in oxazines under salt-free conditions using malononitrile as reductant. The mild reduction conditions allow the development of a sequence of [4 + 2]-cycloaddition/reductive cleavage, a process that can be considered as an efficient way for the diastereoselective 1,4-aminohydroxylation of 1,3-dienes.
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