4.7 Article

A biphosphine copolymer encapsulated single-site Rh catalyst for heterogeneous regioselective hydroaminomethylation of alkenes

Journal

CHEMICAL COMMUNICATIONS
Volume 58, Issue 58, Pages 8093-8096

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc02469a

Keywords

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Funding

  1. National Natural Science Foundation of China [21955207, 22102195]
  2. Natural Science Foundation of Gansu Province, China
  3. Major Project of Gansu Province, China [21JR7RA096, 21ZD4WA021]

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A novel porous organic polymer catalyst was developed for the heterogeneous hydroaminomethylation of alkenes, resulting in improved regioselectivity.
A novel porous organic polymer catalyst with in situ encapsulated single-site Rh (Rh@CPOL-DPMphos&p-3vPPh(3)) was developed and employed in heterogeneous hydroaminomethylation of alkenes, affording the corresponding amines in good to excellent regioselectivity and catalytic activity by a one-pot method. The combined actions of hierarchical pore confinement and the biphosphine ligand derived from the POP catalyst contributed to the improved regioselectivity.

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