Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 3, Issue 9, Pages 1111-1115Publisher
CHINESE CHEMICAL SOC
DOI: 10.1039/c6qo00270f
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Funding
- National Natural Science Foundation of China [21325209, 81521005]
- Shanghai Municipal Committee of Science and Technology [14xd1404400]
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A palladium-catalyzed highly efficient and atom-economical intramolecular cross dehydrogenative coupling (CDC) reaction to access fused polyheterocycles containing a coumarin nucleus has been developed. A wide range of coumestans and indole[3,2-c]coumarins can be afforded in good to excellent yields (up to 99%). By taking advantage of this methodology, some biologically active molecules such as coumestrol and flemichapparin C can be facilely constructed in great yields.
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