Journal
DALTON TRANSACTIONS
Volume 51, Issue 29, Pages 10983-10991Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt01177h
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Funding
- National Natural Science Foundation of China [21871275]
- Nature Science Foundation of Hebei Province [B2019205149]
- Talent Introduction Foundation of Hebei Agricultural University [YJ201931]
- Discipline Group Construction Foundation of Forestry College of Hebei Agricultural University [XK1008601519]
- Research Project of Fundamental Scientific Research Business Expenses of Provincial Colleges and Universities in Hebei Province [KY2021028]
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Molybdenum complexes with various structural features were developed and showed high activity in the transfer hydrogenation reaction. The products can be easily purified by removing the byproduct.
Molybdenum complexes ligated with N-1,N-1-dialkyl-N-2-(5,6,7,8-tetrahydroquinolin-8-yl)ethane-1,2-diamines and auxiliary ligands, providing various structural features, were developed: [NNH/NNHN]Mo(CO)(4/3) (Mo1-Mo3), [NNHN]Mo(CO)(2)Br (Mo4-Mo5), [NNH]Mo(CO)(eta(3)-C3H5)Br (Mo6) and [NNHN/S]Mo(CO)(PPh3)(2) (Mo7-Mo8). All the complexes were highly active in the transfer hydrogenation (TH) of a model substrate (acetophenone), providing excellent yields of 1-phenylethanol. The structural variation in the ligand framework had a modest effect on the catalyst performance as compared to the changes in the auxiliary ligands Br, PPh3 and CO. This structural evolution provided the complex [Mo(NNH)(eta(3)-C3H5)(CO)(2)Br] (Mo6) as the most effective catalyst not only for the transfer hydrogenation of acetophenone but also for a wide range of diverse ketones (up to 43 examples). Moreover, easy purification of the products by only removing the acetone byproduct is another noteworthy feature of this environmentally friendly route.
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