Journal
POLYMER CHEMISTRY
Volume 13, Issue 26, Pages 3870-3875Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2py00490a
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Funding
- National Natural Science Foundation of China [21971015, 21774014]
- Key Laboratory of Cluster Science of Ministry of Education
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Commercially available palladium salts as single-component catalysts can polymerize various 1-chloro-2-phenylacetylenes in air without a cocatalyst, showing advantages of low cost, stability, environmental friendliness, and broad applicability.
Commercially available palladium salts (1-4) (1: PdCl2; 2: PdCl2(CH3CN)(2); 3: PdCl2(C6H5CN)(2); and 4: Pd(OAc)(2)) served as low-cost, stable, green, broad-spectrum, and single-component catalysts with low sensitivity toward functional groups and solvents during the coordination polymerization of various 1-chloro-2-phenylacetylenes, Cl-C C-C6H4R (a-j), in air without a cocatalyst, providing a new metal catalyst design concept for the coordination polymerization of disubstituted alkynes.
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