Photochromism of colloidal ZnO nanocrystal powders under ambient conditions

Zinc oxide (ZnO) nanocrystals (NCs) exhibit photochromic reactions under specific conditions upon ultraviolet light irradiation. Since the color is originated from the excited electrons at the conduction band of ZnO NCs, the photoinduced absorption is observed only in the solution with hole acceptors under inert conditions. ZnO is earth-abundant and less toxic than many other substances, and has been widely used in various industrial fields. If the photochromic reaction of ZnO can be observed consistently under ambient conditions, the material may pave the way for large-scale photochromic applications such as in pigments, windows, and building materials in addition to conventional photochromic applications. In this study, we synthesize hydrophilic ZnO NCs and observe the solid-state photochromic reactions in the visible to mid-infrared regions even in humid-air conditions. We reveal that the coloration of powders of ZnO NCs under ambient conditions originates mainly from two factors: (1) charge separation induced by hole trapping by water molecules adsorbed on the surface of NCs, and (2) deceleration of the reactions involving the electrons in the conduction band of ZnO NCs with molecular oxygen and the adsorbed water molecules.

Automated summary

This study demonstrates the solid-state photochromic reactions of zinc oxide nanocrystals (NCs) in the visible to mid-infrared regions even under humid-air conditions. The reactions are mainly attributed to charge separation induced by water molecules adsorbed on the surface of NCs, as well as the deceleration of reactions involving the electrons in the conduction band with molecular oxygen and adsorbed water molecules.