Porphyrin derivative-based tandem response nanochannels triggered by Zn2+ and NO

We describe tandem response solid nanochannels tailored with a porphyrin derivative that show Zn2+ and NO gating behaviors with good selectivity, stability, and reversibility. EXAFS and fluorescence experiments showed that zinc coordinated with the porphyrin derivative as the ratio of 1 : 1 with the binding constant for 3.39 x 10(5) M-1. These studies are beneficial for simulating the physiological functions of ion/gas in organisms and have the potential for designing complicated logic circuits and fabricating novel biosensors.

Automated summary

We describe tandem response solid nanochannels tailored with a porphyrin derivative that exhibit excellent zinc and nitric oxide gating behaviors. The coordination of zinc with the porphyrin derivative has been confirmed using EXAFS and fluorescence experiments, with a binding constant of 3.39 x 10(5) M-1. These studies have important implications for simulating physiological functions, designing complex logic circuits, and fabricating novel biosensors.