Journal
CHEMICAL SOCIETY REVIEWS
Volume 51, Issue 15, Pages 6307-+Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cs00983d
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Funding
- National Natural Science Foundation of China [21971153]
- Major Basic Research Projects of Shandong Provincial Natural Science Foundation [ZR2020ZD32]
- Taishan Scholars Climbing Program of Shandong Province
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Covalent organic frameworks (COFs) are a class of organic crystalline porous materials with high crystallinity and intrinsic porosity. Metalated COFs formed by combining COFs with metal ions not only retain the advantages of COFs but also have additional properties and applications, thus attracting considerable attention.
Covalent organic frameworks (COFs) are a class of organic crystalline porous materials discovered in the early 21st century that have become an attractive class of emerging materials due to their high crystallinity, intrinsic porosity, structural regularity, diverse functionality, design flexibility, and outstanding stability. However, many chemical and physical properties strongly depend on the presence of metal ions in materials for advanced applications, but metal-free COFs do not have these properties and are therefore excluded from such applications. Metalated COFs formed by combining COFs with metal ions, while retaining the advantages of COFs, have additional intriguing properties and applications, and have attracted considerable attention over the past decade. This review presents all aspects of metalated COFs, from synthetic strategies to various applications, in the hope of promoting the continued development of this young field.
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