Recent advances in bimetallic metal-organic frameworks (BMOFs): synthesis, applications and challenges

Article Engineering, Environmental

Fe doped bimetallic HKUST-1 MOF with enhanced water stability for trapping Pb(II) with high adsorption capacity

Prateek Goyal et al.

Summary: Doping of iron into HKUST-1 MOF significantly enhanced its hydrostability and lead (II) removal efficiency. Fe doped HKUST-1 MOFs showed greater surface area retention and minimal loss in crystallinity.

CHEMICAL ENGINEERING JOURNAL (2022)

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Review Chemistry, Inorganic & Nuclear

Bimetallic metal-organic frameworks and MOF-derived composites: Recent progress on electro- and photoelectrocatalytic applications

Yingtang Zhou et al.

Summary: MOFs have gained attention as versatile electro- and photoelectrocatalytic platforms, offering advantages such as high surface area, porosity, and structural tunability. Bimetallic MOFs and their composites show improved electrical conductivity and electrochemical activity, making them promising for sustainable energy conversion.

COORDINATION CHEMISTRY REVIEWS (2022)

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Article Chemistry, Inorganic & Nuclear

Kinetics-Favorable Ultrathin NiCo-MOF Nanosheets with Boosted Pseudocapacitive Charge Storage for Quasi-Solid-State Hybrid Supercapacitors

Han Li et al.

Summary: In this study, a high-performance bimetallic metal-organic framework with an ultrathin structure is designed, which significantly enhances pseudocapacitive performance and electrochemical kinetics. The quasi-solid-state hybrid supercapacitor based on this framework exhibits desirable energy density, power density, remarkable cyclability, and capability of driving miniature electronics.

INORGANIC CHEMISTRY (2022)

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Article Chemistry, Physical

A chainmail effect of ultrathin N-doped carbon shell on Ni2P nanorod arrays for efficient hydrogen evolution reaction catalysis

Heng Zhang et al.

Summary: The innovative chainmail design enhances the activity and stability of water splitting reactions, with Ni2P@NC/NF showing better performance under alkaline and neutral conditions compared to pure Ni2P, along with high Faradaic efficiency.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Article Chemistry, Multidisciplinary

Photocatalytic degradation of Rhodamine B in aqueous phase by bimetallic metal-organic framework M/Fe-MOF (M = Co, Cu, and Mg)

Thi Kim Ngan Tran et al.

Summary: Bimetallic metal-organic frameworks (MOFs) exhibit outstanding performance in various applications. In this study, M/Fe-MOF materials (M = Co, Cu, and Mg) were synthesized and characterized, showing uniform grain grade and high crystallinity. These materials also demonstrated high photocatalytic degradation of RhB organic pigments under visible light.

OPEN CHEMISTRY (2022)

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Article Chemistry, Physical

Monodispersed ruthenium nanoparticles interfacially bonded with defective nitrogen-and-phosphorus-doped carbon nanosheets enable pH-universal hydrogen evolution reaction

Wenqiang Li et al.

Summary: In this study, the kinetics of hydrogen evolution reaction (HER) was significantly accelerated by interfacially bonding ruthenium nanoparticles with defect-rich nitrogen and phosphorus co-doped carbon nanosheets. The optimal catalyst achieved ultralow overpotentials in alkaline, neutral, and acidic electrolytes, demonstrating excellent pH-universal HER activities. The study revealed the importance of interfacial bonds in modulating the intrinsic kinetics of HER.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Biophysics

Manganese complexes and manganese-based metal-organic frameworks as contrast agents in MRI and chemotherapeutics agents: Applications and prospects

Rouqiao Zheng et al.

Summary: Manganese-based Metal-organic Frameworks (Mn-MOFs) have significant potential in biomedical applications, especially in imaging, anti-tumor therapy, and antimicrobial applications. The low toxicity, oxidative ability, and biocompatibility of Mn-MOFs make them highly desirable in medical field. Manganese complexes also show promising prospects in drug targeting.

COLLOIDS AND SURFACES B-BIOINTERFACES (2022)

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Article Chemistry, Physical

The extra-large calixarene-based MOFs-derived hierarchical composites for photocatalysis of dye: Facile syntheses and contribution of carbon species

Congying Rao et al.

Summary: In this study, Cu/C composites were prepared by calcining synthesized metal-organic nanocapsules precursors and their photocatalytic performance was evaluated for methyl violet degradation. The influence of calcination temperature and time on catalytic activity was investigated, and the Cu@C-100 0-4 composites showed the highest photodegradation performance. The possible mechanism for the degradation of MV dye by Cu/C-100 0-4 composite was analyzed using LC-MS methodology.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

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Article Chemistry, Physical

Highly-stable cobalt metal organic framework with sheet-like structure for ultra-efficient water oxidation at high current density

Zhenjie Lu et al.

Summary: This study successfully synthesized cobalt metal organic frameworks (Co-MOFs) with excellent oxygen evolution performance using a solvothermal strategy, demonstrating high electrocatalytic activity and long-term stability, which could inspire the rational design of high-performance electrocatalysts for water oxidation.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Article Chemistry, Inorganic & Nuclear

Bimetallic MOFs with tunable morphology: Synthesis and enhanced lithium storage properties

Shuhua He et al.

Summary: By doping with cobalt ions during synthesis process, the morphology and lithium storage properties of bimetallic metal-organic frameworks can be improved. The Co-Ni-MOF electrode exhibits high specific capacity and good cyclic rate performance.

JOURNAL OF SOLID STATE CHEMISTRY (2022)

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Article Chemistry, Inorganic & Nuclear

Zn Metal-Organic Framework with High Stability and SorptionSelectivity for CO2

Shuhua Zhang et al.

Summary: In this study, a three-dimensional network with high stability and high adsorption selectivity was synthesized by employing 5-amino-1H-tetrazole and pyromellitic acid ligands to assemble with Zn2+ ions. The study revealed two types of binding sites for CO2 molecules in the network.

ORGANOMETALLICS (2022)

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Article Chemistry, Multidisciplinary

Topology- and Guest-Dependent Photoelectric Conversion of 2D Anionic Pyrene-Based Metal-Organic Framework

Jian-Hua Qin et al.

Summary: Interchromophoric interactions are crucial for the development of unique optoelectronic functionalities in pyrene-based MOFs. In this study, a 2D anionic pyrene-based MOF was synthesized and its photoelectric conversion performance was investigated through the encapsulation of cation dyes. The results showed that the encapsulation of dyes could significantly enhance the absorption range and improve the photoelectric conversion performance of the MOF.

CRYSTAL GROWTH & DESIGN (2022)

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Article Chemistry, Multidisciplinary

Studies on the removal of phosphate in water through adsorption using a novel Zn-MOF and its derived materials

Yujie Zhang et al.

Summary: A novel zinc-based metal-organic framework (Zn-MOF) was prepared and carbonized to investigate its phosphate adsorption performance. The results showed that carbonized Zn-MOF-500 exhibited a larger surface area and higher adsorption capacity for phosphate ions, primarily through monolayer adsorption.

ARABIAN JOURNAL OF CHEMISTRY (2022)

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Article Chemistry, Physical

A multimodal Metal-Organic framework based on unsaturated metal site for enhancing antitumor cytotoxicity through Chemo-Photodynamic therapy

Qiongjie Ding et al.

Summary: Chemodynamic therapy combined with chemotherapy has the potential to revolutionize cancer treatment. This study introduces a new multifunctional platform that combines chemotherapy and photodynamic therapy. The platform demonstrates excellent targeting ability and efficient antitumor activity, offering a novel approach to designing and constructing carriers with dual therapy functionalities.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Article Engineering, Environmental

Cobalt-seamed C-methylpyrogallol[4]arene nanocapsules-derived magnetic carbon cubes as advanced adsorbent toward drug contaminant removal

Ying Pan et al.

Summary: In this study, Co@C composites with incredibly high adsorption capacity for CPZ removal were successfully designed and fabricated. The composites exhibited interconnected micro-and mesoporous structures, well-dispersed Co adsorption active sites, and superior recycling ability.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Engineering full hollow and yolk-shell structures of Z-scheme photocatalysts for advanced hydrogen production

Qingsong Zhang et al.

Summary: The report focused on the preparation and performance of two types of Z-scheme photocatalysts, namely IBS and IBO. Through analysis, it was found that IBS and IBO exhibited excellent performance in H-2 production rate, indicating that their hierarchical hollow structures and Z-scheme heterojunction played a key role in enhancing photocatalytic performance.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Multidisciplinary

(Zn/Co)-zeolitic imidazolate frameworks: Room temperature synthesis and application as promising U(VI) scavengers - A comparative study

Satvir Singh et al.

Summary: The study focuses on utilizing ZIFs as efficient adsorbents for uranium removal from water resources. The ZIFs exhibited high adsorption efficiency and regeneration ability, making them suitable for practical applications in water purifiers. They were found to be effective in treating uranium-contaminated groundwater samples.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Conductive CuCo-Based Bimetal Organic Framework for Efficient Hydrogen Evolution

Bo Geng et al.

Summary: Incorporation of Co into Cu-CAT nanorod arrays improves the efficiency of hydrogen evolution reaction with lower overpotentials, optimized adsorption energy for hydrogen and water, and acceleration of reaction steps, opening a new pathway for the rational design of highly efficient MOF-based electrocatalysts.

ADVANCED MATERIALS (2021)

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Article Engineering, Chemical

Bimetallic Fe-Cu-Based Metal-Organic Frameworks as Efficient Adsorbents for Gaseous Elemental Mercury Removal

Zhen Zhang et al.

Summary: The synthesized FeCu-MOFs exhibited good crystallinity and high elemental dispersity, with excellent Hg-0 removal efficiency higher than 90% in various conditions. The presence of O-2, HCl, and NO in flue gas improved the Hg-0 removal efficiency, while the FeCu-MOFs materials showed good resistance to water vapor and SO2 poisoning. The mercury equilibrium adsorption capacity of FeCu-MOFs was determined to be 12.27 mg/g, and the mercury removal process followed the Langmuir-Hinshelwood mechanism.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021)

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Review Chemistry, Inorganic & Nuclear

Multicomponent isoreticular metal-organic frameworks: Principles, current status and challenges

Archisman Dutta et al.

Summary: Multicomponent Isoreticular Metal-Organic Frameworks (MI-MOFs) are materials designed with multiple linkers or mixed-metals as secondary building units, showing potential in various fields, but face challenges in controlling the periodicity and long-range order of components.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Engineering, Environmental

Iron-nickel bimetallic metal-organic frameworks as bifunctional Fenton-like catalysts for enhanced adsorption and degradation of organic contaminants under visible light: Kinetics and mechanistic studies

Qiangshun Wu et al.

Summary: Iron-nickel bimetallic organic frameworks were developed as bifunctional materials for adsorption and photo-Fenton degradation of organic dyes with different charge properties. The enhanced adsorption capacity and degradation performance were attributed to factors such as enlarged specific surface area, pore volume, and decreased surface charges induced by Ni doping. The dual objectives of in-situ decontamination and adsorbent regeneration were achieved, showcasing advantages like wider pH working range, better stability, and reusability of catalysts.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Chemistry, Inorganic & Nuclear

Efficient Energy-Transfer-Induced High Photoelectric Conversion in a Dye-Encapsulated Ionic Pyrene-Based Metal-Organic Framework

Jian-Hua Qin et al.

Summary: The relationship between the aggregation states of pyrene-based linkers and the photoluminescence/photoelectric performance was investigated by forming an anionic metal-organic framework. Encapsulating D-pi-A cation dyes showed significant enhancement in light-harvesting and photoelectric conversion efficiency.

INORGANIC CHEMISTRY (2021)

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Article Engineering, Electrical & Electronic

Surface engineering of CdS quantum dots modified SiO2@C3N4 nanospheres for effective photocatalytic hydrogen evolution

Manzhou Hong et al.

Summary: The enhanced hydrogen evolution performance of the new composite photocatalyst SiO2@C3N4-CdS QDs is achieved through the synergistic effect of optimized internal structure and heterojunction formation.

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING (2021)

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Review Chemistry, Multidisciplinary

Transition metal-based metal-organic frameworks for environmental applications: a review

Yeisy C. Lopez et al.

Summary: Rapid industrialization is deteriorating air and water quality, leading to the need for efficient and affordable remediation strategies. Metal-organic frameworks (MOFs) are emerging materials for environmental remediation applications, with unique properties for the removal and conversion of pollutants. Transition metal frameworks have shown promise in capturing and converting gaseous pollutants, while also being studied for the removal of chemical warfare agents.

ENVIRONMENTAL CHEMISTRY LETTERS (2021)

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Article Engineering, Environmental

Reuse of Predesigned Dual-Functional Metal Organic Frameworks (DF-MOFs) after Heavy Metal Removal

Leili Esrafili et al.

Summary: The systematic design of dual-functionalized metal organic frameworks for the removal of heavy metal ions from wastewater is crucial in environmental science. The creation of strong host-guest interactions between cations and donor sites significantly enhances heavy metals uptake. The engineered pore surface of MOFs provides a potential for multifunctional nanoparticles design to meet specific application requirements.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Review Biochemistry & Molecular Biology

Recent Advances in Fe-MOF Compositions for Biomedical Applications

Yuyu Zhong et al.

Summary: This review focuses on the latest studies of applications of Fe-based MIL in biomedicine, including bioimaging, biosensing, antibacterial, and drug delivery. The shortcomings and future perspectives of Fe-based MIL materials in biomedical applications, including dosage and loading strategies, are briefly discussed. Further studies with different therapies will be of great interest.

CURRENT MEDICINAL CHEMISTRY (2021)

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Article Chemistry, Physical

Fine-Tuning the Metal Oxo Cluster Composition and Phase Structure of Ni/Ti Bimetallic MOFs for Efficient CO2 Reduction

Siyuan Chen et al.

Summary: The gradient modulation of metal oxo cluster components in Ni/Ti bimetallic MOFs, achieved by tuning the molar ratio of Ni2+/Ti4+, enhances photocatalytic activity by improving charge separation and transfer, providing more opportunities for MOF-based materials design.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

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Article Chemistry, Multidisciplinary

A Tunable Multivariate Metal-Organic Framework as a Platform for Designing Photocatalysts

Yang Wang et al.

Summary: This study presents a series of novel multivariate metalorganic frameworks (MTV-MOFs) denoted as MTV-MIL-100, constructed by ordered metal clusters that enhance electronic structures of crystalline materials and improve mass transport utilizing the high porosity of the MOF structure.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Review Chemistry, Multidisciplinary

A Review of MOFs and Their Composites-Based Photocatalysts: Synthesis and Applications

Yongteng Qian et al.

Summary: MOFs-based photocatalysts have unique morphology, high performance, stability, easy synthesis, and low cost. This review introduces synthetic strategies, summarizes various types of MOFs composite photocatalysts, and highlights different applications of MOFs-based photocatalysts.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Inorganic & Nuclear

New highly luminescent 3D Tb(III)-MOF as selective sensor for antibiotics

Gang Li et al.

Summary: A stable 3D metal-organic framework (MOF) has been synthesized and characterized, showing intense green emission and sensitivity towards sulfamethazine (SMZ) as a luminescent sensor. The MOF also exhibits excellent stability and recyclability, and the mechanism of deterioration in luminescence intensity in the presence of antibiotics has been explained through theoretical calculations and Hirshfeld surface analyses.

INORGANIC CHEMISTRY COMMUNICATIONS (2021)

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Article Materials Science, Multidisciplinary

Controllable preparation and capacitance performance of bimetal Co/Ni-MOF

Hui-ya Chen et al.

Summary: In this study, bimetal Co/Ni organic framework material (Co/Ni-MOF) was successfully prepared by adjusting the concentration of inserted metal Ni to control its electrochemical performance. The material exhibited excellent cycling stability and high energy density when assembled into supercapacitors, making it a promising electrode material for supercapacitor devices.

SYNTHETIC METALS (2021)

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Article Chemistry, Physical

Boosting Nitrogen Activation via Bimetallic Organic Frameworks for Photocatalytic Ammonia Synthesis

Zhanfeng Zhao et al.

Summary: The study proposed a strategy for boosting N-2 activation by decoupling the electron acceptance and donation processes using bimetallic organic frameworks (BMOFs). Through testing six different bimetal combinations, it was found that a specific ionization potential difference and metal proportion led to a dominant bimetal synergistic effect. The optimal BMOF(Sr)-0.2Fe photocatalyst exhibited a high NH3 evolution rate, highlighting a potential breakthrough in catalytic processes.

ACS CATALYSIS (2021)

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Article Chemistry, Inorganic & Nuclear

A new magnetic adsorbent of eggshell-zeolitic imidazolate framework for highly efficient removal of norfloxacin

Yuyu Zhong et al.

Summary: A magnetic biocomposite was designed and synthesized to remove antibiotics from effluents, showing a high removal efficiency for norfloxacin. The adsorbent exhibited easy separation from the aqueous solution due to its magnetic nature.

DALTON TRANSACTIONS (2021)

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Review Chemistry, Inorganic & Nuclear

Alkali /alkaline earth-based metal-organic frameworks for biomedical applications

Gaomin Ye et al.

Summary: Alkali/alkaline earth metal MOFs are gaining attention due to their excellent biocompatibility, offering potential for broader applications in biomedicine. This review introduces their applications in drug delivery, sensing, and unique biomedical materials, while discussing the challenges and development prospects in the biomedical field.

DALTON TRANSACTIONS (2021)

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Review Chemistry, Multidisciplinary

Biomedical applications of metal-organic framework (MOF)-based nano-enzymes

Yuzhi Qiu et al.

Summary: Nano-enzymes are nano materials that mimic the catalytic function of enzymes and serve as substitutes for natural enzymes due to their excellent properties. Metal-organic frameworks (MOFs) and their derivatives represent a promising class of nano-enzymes with potential applications in biomedicine.

NEW JOURNAL OF CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Series of highly stable Cd(II)-based MOFs as sensitive and selective sensors for detection of nitrofuran antibiotic

Shanhe Zhou et al.

Summary: The misuse of antibiotics has led to global issues, and the synthesis of four new metal-organic frameworks with various topologies has allowed for the detection of 11 types of antibiotics through fluorescence quenching effect, with sample 2 showing sensitive and selective detection for nitrofurantoin (NZF). This highly selective probe behavior towards NZF ions can be maintained even in the presence of other interfering antibiotics.

CRYSTENGCOMM (2021)

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Article Chemistry, Multidisciplinary

High loading of Mn(ii)-metalated porphyrin in a MOF for photocatalytic CO2 reduction in gas-solid conditions

Jian-Hua Qin et al.

Summary: The 2D porphyrin-based Mn-MOF, with high loading of Mn(ii)-metalated porphyrin induced by an ionic liquid, exhibits excellent stability, sufficient redox potential, atomically dispersed porphyrin Mn(ii) sites, desired CO2 affinity, high visible light-harvesting, and efficient charge separation, enabling overall photocatalytic conversion of CO2 to CH4 in gas-solid conditions.

CHEMICAL COMMUNICATIONS (2021)

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Article Chemistry, Organic

Chemoselective hydroborative reduction of nitro motifs using a transition-metal-free catalyst

Wubing Yao et al.

Summary: The study introduced a novel transition-metal-free strategy for chemoselective catalytic reduction of nitro scaffolds to valuable amine functions under mild reaction conditions, which can be readily applied to the preparation of commercially available pharmaceuticals.

ORGANIC CHEMISTRY FRONTIERS (2021)

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Article Chemistry, Physical

Syntheses, design strategies, and photocatalytic charge dynamics of metal-organic frameworks (MOFs): a catalyzed photo-degradation approach towards organic dyes

Ayushi Singh et al.

Summary: Metal-organic frameworks (MOFs) and coordination polymers (CPs) are new varieties of materials with potential applications in gas separation, storage, membranes, and drug delivery. Recent research explores the use of pure MOFs as photocatalysts, with computational studies providing insights into their photocatalytic properties. These materials show promise in degrading organic molecules, particularly dyes, in wastewater discharge from industrial sources.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

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Review Materials Science, Biomaterials

Recent advances in cell membrane coated metal-organic frameworks (MOFs) for tumor therapy

Weicong Liu et al.

Summary: Using cell membrane coating technology to improve the tumor-targeting ability of metal-organic frameworks has shown promising results, but faces challenges in further development and application due to technological limitations.

JOURNAL OF MATERIALS CHEMISTRY B (2021)

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Article Materials Science, Multidisciplinary

Robust lanthanide metal-organic frameworks with all-in-one multifunction: efficient gas adsorption and separation, tunable light emission and luminescence sensing

Bo Li et al.

Summary: In this study, a series of lanthanide metal-organic frameworks were constructed with multifunctional capabilities, including excellent gas adsorption and separation, tunable light emission, and efficient luminescence sensing. The materials showed potential for addressing industrially important separation challenges and were suitable for barcode applications, highlighting their versatility and potential for various applications.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Article Chemistry, Multidisciplinary

Efficient photocatalytic degradation of methyl violet using two new 3D MOFs directed by different carboxylate spacers

Jun Wang et al.

Summary: Two highly stable metal-organic frameworks were designed and synthesized, showing outstanding photocatalytic behaviors for the disintegration of methyl violet under UV irradiation, using different assembly materials.

CRYSTENGCOMM (2021)

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Article Chemistry, Applied

Multi-functional fluorescent responses of cobalt complexes derived from functionalized amide-bridged ligand

Guo Cheng Liu et al.

DYES AND PIGMENTS (2020)

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Article Electrochemistry

Self-assembled bimetallic cobalt-manganese metal-organic framework as a highly efficient, robust electrode for asymmetric supercapacitors

Youngho Seo et al.

ELECTROCHIMICA ACTA (2020)

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Article Engineering, Environmental

High capacity Hg(II) and Pb(II) removal using MOF-based nanocomposite: Cooperative effects of pore functionalization and surface-charge modulation

Nasrin Abdollahi et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

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Article Nanoscience & Nanotechnology

Bimetallic MOF Nanosheets Decorated on Electrospun Nanofibers for High-Performance Asymmetric Supercapacitors

Di Tian et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Engineering, Environmental

Bimetallic metal-organic frameworks (MOFs) synthesized using the spray method for tunable CO2 adsorption

Xiang He et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Review Chemistry, Multidisciplinary

Metal-Organic Frameworks for the Removal of Emerging Organic Contaminants in Water

Sara Rojas et al.

CHEMICAL REVIEWS (2020)

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Article Chemistry, Multidisciplinary

Lithium-Lanthanide Bimetallic Metal-Organic Frameworks towards Negative Electrode Materials for Lithium-Ion Batteries

Xiao-Yi Song et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

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Review Chemistry, Inorganic & Nuclear

Recent developments in luminescent coordination polymers: Designing strategies, sensing application and theoretical evidences

Jian-Qiang Liu et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Article Chemistry, Inorganic & Nuclear

Investigation of the Effect of a Mixed-Ligand on the Accommodation of a Templating Molecule into the Structure of High-Nucleus Silver Clusters

Kuan-Guan Liu et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Physical

A high-performance battery-supercapacitor hybrid device based on bimetallic hydroxides nanoflowers derived from metal -organic frameworks

Qi Li et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2020)

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Article Chemistry, Inorganic & Nuclear

Hexavalent Octahedral Template: A Neutral High-Nucleus Silver Alkynyl Nanocluster Emitting Infrared Light

Kuan-Guan Liu et al.

INORGANIC CHEMISTRY (2020)

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Article Spectroscopy

Selective sensing of Fe3+ ions in aqueous solution by a biodegradable platform based lanthanide metal organic framework

Peng Jia et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2020)

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Article Nanoscience & Nanotechnology

Bimetallic Lanthanide-Organic Framework Membranes as a Self- Calibrating Luminescent Sensor for Rapidly Detecting Antibiotics in Water

Jie Dong et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Organic

Combined KOH/BEt3 Catalyst for Selective Deaminative Hydroboration of Aromatic Carboxamides for Construction of Luminophores

Wubing Yao et al.

ORGANIC LETTERS (2020)

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Review Chemistry, Multidisciplinary

Electrochemical Applications of Ferrocene-Based Coordination Polymers

Mao-Lin Hu et al.

CHEMPLUSCHEM (2020)

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Article Chemistry, Inorganic & Nuclear

Size-Selective Urea-Containing Metal-Organic Frameworks as Receptors for Anions

Leili Esrafili et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Ionic liquid induced highly dense assembly of porphyrin in MOF nanosheets for photodynamic therapy

Jian-Hua Qin et al.

DALTON TRANSACTIONS (2020)

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Article Chemistry, Physical

A nickel and cobalt bimetal organic framework with high capacity as an anode material for lithium-ion batteries

Wen Zheng et al.

SUSTAINABLE ENERGY & FUELS (2020)

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Article Chemistry, Inorganic & Nuclear

A versatile and multifunctional metal-organic framework nanocomposite toward chemo-photodynamic therapy

Ying Pan et al.

DALTON TRANSACTIONS (2020)

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Article Chemistry, Physical

A conductive 1D high-nucleus silver polymer as a brilliant non-hybrid supercapacitor electrode

Kuan-Guan Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Review Chemistry, Multidisciplinary

Metal-organic frameworks as a platform for clean energy applications

Xinran Li et al.

ENERGYCHEM (2020)

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Review Chemistry, Inorganic & Nuclear

Sensing organic analytes by metal-organic frameworks: a new way of considering the topic

Mao-Lin Hu et al.

INORGANIC CHEMISTRY FRONTIERS (2020)

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Article Chemistry, Applied

Atom- and step-economic synthesis of π-conjugated large oligomers via C-H activated oligomerization

Shi-Yong Liu et al.

DYES AND PIGMENTS (2019)

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Article Environmental Sciences

Cu and Co nanoparticles co-doped MIL-101 as a novel adsorbent for efficient removal of tetracycline from aqueous solutions

Jiahui Jin et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2019)

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Review Chemistry, Multidisciplinary

Porous metal-organic frameworks as emerging sorbents for clean air

Xue Han et al.

NATURE REVIEWS CHEMISTRY (2019)

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Review Chemistry, Inorganic & Nuclear

Template strategies with MOFs

Mao-Lin Hu et al.

COORDINATION CHEMISTRY REVIEWS (2019)

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Article Chemistry, Multidisciplinary

Highly Conductive Bimetallic Ni-Fe Metal Organic Framework as a Novel Electrocatalyst for Water Oxidation

Fuqin Zheng et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

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Article Chemistry, Multidisciplinary

One-Pot Synthesis of Heterobimetallic Metal-Organic Frameworks (MOFs) for Multifunctional Catalysis

Bushra Iqbal et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

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Article Chemistry, Multidisciplinary

Design of a 1,8-naphthalimide-based OFF-ON type bioorthogonal reagent for fluorescent imaging in live cells

Zhuzhou Shao et al.

CHINESE CHEMICAL LETTERS (2019)

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Article Chemistry, Multidisciplinary

Theoretical study of metal ion impact on geometric and electronic properties of terbutaline compounds

Zhong Ai Guo et al.

MONATSHEFTE FUR CHEMIE (2019)

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Editorial Material Chemistry, Physical

How to Effectively Utilize MOFs for Electrocatalysis

Song Jin

ACS ENERGY LETTERS (2019)

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Article Nanoscience & Nanotechnology

High Ion Transport within a Freeze-Casted Gel Film for High-Rate Integrated Flexible Supercapacitors

Yang Bai et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Electrochemistry

Calcination/phosphorization of dual Ni/Co-MOF into NiCoP/C nanohybrid with enhanced electrochemical property for high energy density asymmetric supercapacitor

Qingfeng Zhou et al.

ELECTROCHIMICA ACTA (2019)

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Article Engineering, Chemical

Effective Capture of Cefradines in Water with a Highly Stable Zr(IV)-Based Bimetal-Organic Framework

Yitian Zhou et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

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Article Chemistry, Physical

Fe/Ni bimetal organic framework as efficient oxygen evolution catalyst with low overpotential

Fuqin Zheng et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2019)

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Review Nanoscience & Nanotechnology

Recent Progress on Engineering Highly Efficient Porous Semiconductor Photocatalysts Derived from Metal-Organic Frameworks

Wenwen Zhan et al.

NANO-MICRO LETTERS (2019)

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Review Chemistry, Physical

Metal-organic frameworks and their derivatives for metal-air batteries

Bingjun Zhu et al.

ENERGY STORAGE MATERIALS (2019)

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Article Chemistry, Physical

Exploring the catalytic performance of a series of bimetallic MIL-100(Fe, Ni) MOFs

Monica Gimenez-Marques et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Multidisciplinary

A new Zn(ii)-based 3D metal-organic framework with uncommon sev topology and its photocatalytic properties for the degradation of organic dyes

Ying Pan et al.

CRYSTENGCOMM (2019)

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Article Chemistry, Multidisciplinary

A two-dimensional multi-shelled metal-organic framework and its derived bimetallic N-doped porous carbon for electrocatalytic oxygen reduction

Yang Xu et al.

CHEMICAL COMMUNICATIONS (2019)

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Molecular Acidity: An Accurate Description with Information-Theoretic Approach in Density Functional Reactivity Theory

Xiaofang Cao et al.

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Nanomaterials derived from metal-organic frameworks

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Metal-Organic-Framework-Based Catalysts for Photoreduction of CO2

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Exploring the Performance Improvement of the Oxygen Evolution Reaction in a Stable Bimetal-Organic Framework System

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Exploring the Performance Improvement of the Oxygen Evolution Reaction in a Stable Bimetal-Organic Framework System

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Zirconium-Porphyrin-Based Metal-Organic Framework Hollow Nanotubes for Immobilization of Noble-Metal Single Atoms

Ting He et al.

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Engineering Metal-organic Frameworks (MOFs) for Efficient Photocatalysis

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Formation of bimetallic metal-organic framework nanosheets and their derived porous nickel-cobalt sulfides for supercapacitorst

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DALTON TRANSACTIONS (2018)

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One-step synthesis of MnS/MoS2/C through the calcination and sulfurization of a bi-metal-organic framework for a high-performance supercapacitor and its photocurrent investigation

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Adsorption of Pharmaceuticals from Water and Wastewater Using Nonconventional Low-Cost Materials: A Review

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Design strategies for metal-organic frameworks selectively capturing harmful gases

Ki Chul Kim

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Taking organic reactions over metal-organic frameworks as heterogeneous catalysis

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A luminescent Eu(III)-based metal-organic framework as a highly effective sensor for cation and anion detections

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A phase transformable ultrastable titanium-carboxylate framework for photoconduction

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MOF-74 derived porous hybrid metal oxide hollow nanowires for high-performance electrochemical energy storage

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One-step rapid synthesis of π-conjugated large oligomers via C-H activation coupling

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Metal-Organic Frameworks as Platform Materials for Solar Fuels Catalysis

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Metal-organic frameworks for direct electrochemical applications

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Bimetallic-MOF Derived Accordion-like Ternary Composite for High-Performance Supercapacitors

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Nanoscale Trimetallic Metal-Organic Frameworks Enable Efficient Oxygen Evolution Electrocatalysis

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Bimetallic Metal-Organic Frameworks as Efficient Cathode Catalysts for Li-O-2 Batteries

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Metal-Organic Frameworks as Platforms for Catalytic Applications

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Metal-Organic Frameworks for Carbon Dioxide Capture and Methane Storage

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Series d-f Heteronuclear Metal-Organic Frameworks: Color Tunability and Luminescent Probe with Switchable Properties

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Ultrathin metal-organic framework array for efficient electrocatalytic water splitting

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Enhanced adsorptive removal of anionic and cationic dyes from single or mixed dye solutions using MOF PCN-222

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Mixed-metallic MOF based electrode materials for high performance hybrid supercapacitors

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Template-directed synthesis of a luminescent Tb-MOF material for highly selective Fe3+ and Al3+ ion detection and VOC vapor sensing

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Metal-organic frameworks: functional luminescent and photonic materials for sensing applications

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Enhancing Proton Conductivity in a 3D Metal-Organic Framework by the Cooperation of Guest [Me2NH2]+ Cations, Water Molecules, and Host Carboxylates

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An anionic metal-organic framework with ternary building units for rapid and selective adsorption of dyes

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A novel bimetallic MIL-101(Cr, Mg) with high CO2 adsorption capacity and CO2/N2 selectivity

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The Uncommon Channel-Based Ln-MOFs for Highly Selective Fe3+ Detection and Superior Rhodamine B Adsorption

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Systematic and Dramatic Tuning on Gas Sorption Performance in Heterometallic Metal-Organic Frameworks

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Transition metal (Fe, Co, Ni, and Mn) oxides for oxygen reduction and evolution bifunctional catalysts in alkaline media

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NANO TODAY (2016)

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NiFe-Based (Oxy)hydroxide Catalysts for Oxygen Evolution Reaction in Non-Acidic Electrolytes

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Room-temperature synthesis of bimetallic Co-Zn based zeolitic imidazolate frameworks in water for enhanced CO2 and H-2 uptakes

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MOF-derived self-sacrificing route to hollow NiS2/ZnS nanospheres for high performance supercapacitors

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Cooperative Cluster Metalation and Ligand Migration in Zirconium Metal-Organic Frameworks

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Thermodynamic parameters of cation exchange in MOF-5 and MFU-4l

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A near infrared luminescent metal-organic framework for temperature sensing in the physiological range

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Metal-organic frameworks for luminescence thermometry

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Revisiting the beryllium bonding interactions from energetic and wavefunction perspectives

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CHEMICAL PHYSICS LETTERS (2015)

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A series of homonuclear lanthanide coordination polymers based on a fluorescent conjugated ligand: syntheses, luminescence and sensor for pollutant chromate anion

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CRYSTENGCOMM (2015)

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Tunable Catalytic Activity of Solid Solution Metal-Organic Frameworks in One-Pot Multicomponent Reactions

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Metal organic framework-mediated synthesis of highly active and stable Fischer-Tropsch catalysts

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Topology-Guided Design and Syntheses of Highly Stable Mesoporous Porphyrinic Zirconium Metal-Organic Frameworks with High Surface Area

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A mini review of NiFe-based materials as highly active oxygen evolution reaction electrocatalysts

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Defining the Proton Topology of the Zr6-Based Metal-Organic Framework NU-1000

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A review of available methods and development on energy storage; technology update

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Energy storage systems for renewable energy power sector integration and mitigation of intermittency

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Zn-doped Ni-MOF material with a high supercapacitive performance

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Prussian blue analogues: a new class of anode materials for lithium ion batteries

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Ratiometric Nanothermometer Based on an Emissive Ln3+-Organic Framework

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ACS NANO (2013)

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A series of Zn-4f heterometallic coordination polymers and a zinc complex containing a flexible mixed donor dicarboxylate ligand

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Tandem Postsynthetic Metal Ion and Ligand Exchange in Zeolitic Imidazolate Frameworks

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Ti3+-, V2+/3+-, Cr2+/3+-, Mn2+-, and Fe2+-Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5

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Tuning the breathing behaviour of MIL-53 by cation mixing

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Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal-Organic Frameworks

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

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Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks

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Advanced Materials for Energy Storage

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Engineering Metal Organic Frameworks for Heterogeneous Catalysis

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Synthesis and Stability of Tagged UiO-66 Zr-MOFs

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High Gas Sorption and Metal-Ion Exchange of Microporous Metal-Organic Frameworks with Incorporated Imide Groups

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CHEMISTRY-A EUROPEAN JOURNAL (2010)

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Metal-Organic Frameworks: Opportunities for Catalysis

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

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CHEMICAL SOCIETY REVIEWS (2009)

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Selective gas adsorption and separation in metal-organic frameworks

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CHEMICAL SOCIETY REVIEWS (2009)

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Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification

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JOURNAL OF MATERIALS CHEMISTRY (2009)

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Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal-Organic Frameworks at Room Temperature

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

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Metathesis in Single Crystal: Complete and Reversible Exchange of Metal Ions Constituting the Frameworks of Metal-Organic Frameworks

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

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Hydrogen adsorption properties of lantern-type dinuclear M(BDC)(DABCO)1/2

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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN (2008)

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Hydrogen storage in the dehydrated Prussian blue analogues M3[Co(CN)6]2 (M = Mn, Fe, Co, Ni, Cu, Zn)

SS Kaye et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

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Recent advances in bimetallic metal-organic frameworks (BMOFs): synthesis, applications and challenges

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