Journal
DALTON TRANSACTIONS
Volume 51, Issue 29, Pages 10856-10859Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt01108e
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Funding
- Natural Science Foundation of Guangdong Province [2019A1515010692]
- National Natural Science Foundation of China [21901166]
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We present the self-assembly of a zirconium-based metal-organic framework with hexanuclear Zr-oxo clusters residing in its pore windows. The structure exhibits microporosity and has a higher affinity for xenon over krypton.
We report here the self-assembly of a she-type zirconium-based metal-organic framework with discrete hexanuclear Zr-oxo clusters residing inside its pore windows. The overall structure features microporosity showing preferential adsorption of Xe over Kr.
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