Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 62, Pages 8710-8713Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc03252j
Keywords
-
Categories
Funding
- NSFC [21825104, 22071091, 21801103]
- China Postdoctoral Science Foundation [2020M683603]
- FRFCU [lzujbky-20210119, lzujbky2021-pd02]
- PCSIRT [IRT_15R28]
Ask authors/readers for more resources
The unique reactivity of indolyl-substituted p-QMs as a new type of two-carbon synthon in a novel iron(iii)-catalyzed tandem annulation has been explored for the first time. The (2+2) annulation/retro-4 pi electrocyclization/imino-Nazarov cyclization cascade reaction is characterized by an unusual structural reconstruction of indolyl-substituted p-QMs, leading to the rapid assembly of synthetically important functionalized cyclopenta[b]indoles.
The unique reactivity of indolyl-substituted p-QMs as a new type of two-carbon synthon has been explored for the first time in a novel iron(iii)-catalyzed tandem annulation. This (2+2) annulation/retro-4 pi electrocyclization/imino-Nazarov cyclization cascade reaction is characterized by an unusual structural reconstruction of indolyl-substituted p-QMs, leading to an expeditious assembly of synthetically important functionalized cyclopenta[b]indoles.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
