Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 63, Pages 8802-8805Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc03155h
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Funding
- ANR (NCO-INNOV) [20-CE07-0015-01]
- University of Bordeaux
- CNRS
- Alex-Ekwueme Federal University NdufuAlike Ikwo (AE-FUNAI)
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Photocatalyzed oxidative decarboxylation of oxamic acids under near-infrared irradiation using Os(bptpy)(2)(PF6)(2) as catalyst is reported. The reaction was applied to the synthesis of urethanes and heterocyclic amides. Mechanistic studies and comparative penetration depths between the NIR and the visible light mediated processes are discussed.
Photocatalyzed oxidative decarboxylation of oxamic acids under near-infrared irradiation using Os(bptpy)(2)(PF6)(2) as catalyst is reported. The reaction was applied to the synthesis of urethanes and heterocyclic amides. Mechanistic studies and comparative penetration depths between the NIR and the visible light mediated processes are discussed.
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