Unraveling high alkene selectivity at full conversion in alkyne hydrogenation over Ni under continuous flow conditions

Selective hydrogenation of alkynes into alkenes under continuous flow conditions over non-precious metal catalysts is an attractive prospect for the chemical industry, especially for the petrochemical and polymer industry. Achieving high alkene selectivity at full alkyne conversions is an ongoing challenge. To address this, we dissolved carbon into Ni lattices by treating Ni@C material derived from MOF-74(Ni) with H-2 at 300 degrees C and the resultant material is explored as a catalyst for selective styrene synthesis from phenylacetylene (PA) under fixed bed flow conditions. The designed catalyst exhibited a rare combination of sustained high styrene (ST) selectivity (92 +/- 1%) and full phenylacetylene (PA) conversion (>99%). Density functional theory (DFT) calculations predict that the carbon incorporation decreases the interaction energy between ST and the catalyst surface, and this increased the reaction barrier for further hydrogenation. Time on stream data showed a 13 h stable performance and the catalyst is regenerable for 4 cycles without a loss of activity. Further, PA is completely removed (by semi-hydrogenation) from the styrene stream even when it is present in low quantities (1.8%).

Automated summary

Selective hydrogenation of alkynes into alkenes using non-precious metal catalysts under continuous flow conditions is a significant development for the chemical industry. In this study, a catalyst with rare combination of high styrene selectivity and full phenylacetylene conversion was designed by dissolving carbon into nickel lattices. The catalyst exhibited stable performance and regenerability for multiple cycles.