Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 10, Issue 29, Pages 10742-10747Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1tc06054f
Keywords
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Funding
- Engineering and Physical Sciences Research Council [EP/S003126/1]
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In this study, a new class of asymmetric indolonaphthyridines (IND) derived using a novel high yielding methodology was presented. The absorption properties and excited state charge-transfer character of these novel asymmetric INDs were compared with symmetric INDs. The results showed that the asymmetry of INDs increased the change in dipole moment and excited state charge-transfer character, which was attributed to the increased spatial separation between excited state electron and hole wavefunctions for the asymmetric INDs. The structure-property relationships introduced in this work provide invaluable design principles for the generation of high performance materials.
Indolonaphthyridines (IND) are valuable chromophores with wide-ranging optoelectronic applications. Here, we present a new class of asymmetric IND derivatives, synthesised using novel high yielding methodology. We compare the absorption properties and excited state charge-transfer character of the novel assymetric INDs with symmetric IND. We show IND assymetry increases the change in dipole moment from ground to excited state. By determining the magnitude of the excited state dipole moment of each IND derivative, we also show assymetry increases excited state charge-transfer character. Quantum calculations indicate this is a consequence of increased spatial separation between excited state electron and hole wavefunctions for the assymetric INDs. Charge-transfer features can significantly benefit many optoelectronic processes, therefore the structure-property relationships introduced in this work provide invaluable design principles for the generation of high performance materials.
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