Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 63, Pages 8830-8833Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc03148e
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Funding
- National Natural Science Foundation of China [21802128, 21725306, 22001240]
- Fundamental Research Funds for the Central Universities [2652019113]
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Highly crystalline Fe-COFs were successfully constructed using a subcomponent assembly strategy. The spectral results confirm the coordination of Fe(ii) ions with the nitrogen atoms of the iminopyridine linkages.
Highly crystalline Fe-COFs were constructed from the building blocks carrying pyridyl-aldehyde and triamine moieties in the presence of Fe(OTf)(2) and acetic acid under ambient conditions via a subcomponent assembly strategy. The spectral results prove the coordination of atomically distributed Fe(ii) ions with the nitrogen species of covalently formed iminopyridine linkages.
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