Journal
DALTON TRANSACTIONS
Volume 51, Issue 31, Pages 11617-11619Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt02152h
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Funding
- EPSRC (MJGS)
- Royal Society (ABC) [UF100592, UF150675]
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A well-defined Pd(i) metalloradical reacts with aryl and alkyl iodides at room temperature, producing [Pd(PtBu3)(mu-I)](2) and phosphonium salts. Pd(ii) aryl/alkyl derivatives, indicating net radical oxidative addition, have been isolated and characterized crystallographically.
The well-defined Pd(i) metalloradical [Pd(PtBu3)(2)](+) reacts with aryl and alkyl iodides at room temperature, yielding [Pd(PtBu3)(mu-I)](2) and phosphonium salts. Pd(ii) aryl/alkyl derivates, reflecting net radical oxidative addition of the substrate to the metalloradical, are generated during the reaction and two examples have been isolated and crystallographically characterised.
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