Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 9, Issue 17, Pages 4670-4675Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qo00843b
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Funding
- National Natural Science Foundation of China [22071218]
- Natural Science Foundation of Zhejiang Province [LZ20B020001, LY20B020006]
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A Cu-catalyzed 5-endo-selective trifluoromethylcarbocyclization of ynones has been developed for the concise synthesis of trifluoromethylated cyclopentenones. The pivotal roles of carbonyl groups in the reaction have been well illustrated by experiments and density functional theory calculations.
A Cu-catalyzed 5-endo-selective trifluoromethylcarbocyclization of ynones is developed for the concise synthesis of trifluoromethylated cyclopentenones. The pivotal roles of carbonyl groups are well illustrated by experiments and density functional theory calculations.
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