Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 66, Pages 9214-9217Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc02891c
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Funding
- National Natural Science Foundation of China [21801206]
- Program for Young Talents of Shaanxi Province [5113190023]
- Natural Science Basic Research Program of Shaanxi [2021JM-049]
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Aryl ketones, an important class of organic compounds, are widely used in the synthesis of pharmaceuticals, biologically active molecules, and functional materials. This study presents a facile synthetic method for the construction of aryl ketones through Ni-catalyzed cross coupling of epoxides with aryltriflates, resulting in highly regioselective conversion with good yields in a redox neutral manner.
Aryl ketones are one of the most important classes of organic compounds, and widely present in various pharmacological compounds, biologically active molecules and functional materials. Presented herein is a facile synthetic method for the construction of ketones via Ni-catalyzed cross coupling of epoxides with aryltriflates. A range of easily accessible epoxides can be highly regioselectively converted to the corresponding aryl ketones with good yields in a redox neutral fashion.
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