Recent developments in high-performance Nafion membranes for hydrogen fuel cells applications

As a promising alternative to petroleum fossil energy, polymer electrolyte membrane fuel cell has drawn considerable attention due to its low pollution emission, high energy density, portability, and long operation times. Proton exchange membrane (PEM) like Nafion plays an essential role as the core of fuel cell. A good PEM must have satisfactory performance such as high proton conductivity, excellent me-chanical strength, electrochemical stability, and suitable for making membrane electrode assemblies (MEA). However, performance degradation and high permeability remain the main shortcomings of Nafion. Therefore, the development of a new PEM with better performance in some special conditions is greatly desired. In this review, we aim to summarize the latest achievements in improving the Nafion performance that works well under elevated temperature or methanol-fueled systems. The methods described in this article can be divided into some categories, utilizing hydrophilic inorganic material, metal-organic frameworks, nanocomposites, and ionic liquids. In addition, the mechanism of proton conduction in Nafion membranes is discussed. These composite membranes exhibit some desirable characteristics, but the development is still at an early stage. In the future, revolutionary approaches are needed to accelerate the application of fuel cells and promote the renewal of energy structure.(c) 2021 The Authors. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/ 4.0/).

Automated summary

Polymer electrolyte membrane fuel cells have gained attention as a promising alternative to petroleum fossil energy due to their low pollution emission, high energy density, portability, and long operation times. However, the performance degradation and high permeability of traditional proton exchange membrane Nafion remain major challenges. This review summarizes the latest achievements in improving the performance of Nafion, particularly for elevated temperature or methanol-fueled systems. Various methods and composite membranes utilizing hydrophilic inorganic material, metal-organic frameworks, nanocomposites, and ionic liquids are discussed. Further revolutionary approaches are needed to accelerate the application of fuel cells and promote the renewal of energy structure.