Ocean alkalinity enhancement - avoiding runaway CaCO3 precipitation during quick and hydrated lime dissolution

Ocean alkalinity enhancement (OAE) is a method that can remove carbon dioxide (CO2) from the atmosphere and counteract ocean acidification through the dissolution of alkaline minerals. Currently, critical knowledge gaps exist regarding the dissolution of different minerals suitable for OAE in natural seawater. Of particular importance is to understand how much alkaline mineral can be dissolved before secondary precipitation of calcium carbonate (CaCO3) occurs, since secondary CaCO3 precipitation reduces the atmospheric CO2 uptake potential of OAE. Using two types of mineral proposed for OAE, quick lime (CaO) and hydrated lime (Ca(OH)(2)), we show that both (<63 mu m of diameter) dissolved in seawater within a few hours. No CaCO3 precipitation occurred at a saturation state (Omega(A)) of similar to 5, but CaCO3 precipitation in the form of aragonite occurred above an Omega(A) value of 7. This limit is lower than expected for typical pseudo-homogeneous precipitation, i.e. in the presence of colloids and organic matter. Secondary precipitation at low Omega(A) ( similar to 7) was the result of heterogeneous precipitation onto mineral surfaces, most likely onto the added CaO and Ca(OH)(2) particles. Most importantly, runaway CaCO3 precipitation was observed, a condition where significantly more total alkalinity (TA) was removed than initially added. Such runaway precipitation could reduce the OAE CO2 uptake efficiency from similar to 0.8 mol of CO2 per mole of added TA down to 0.1 mol of CO2 per mole of TA. Runaway precipitation appears to be avoidable by dilution below the critical Omega(A) threshold of 5, ideally within hours of the mineral additions to minimise initial CaCO3 precipitation. Finally, OAE simulations suggest that for the same Omega(A) threshold, the amount of TA that can be added to seawater would be more than 3 times higher at 5 degrees C than at 30 degrees C. The maximum TA addition could also be increased by equilibrating the seawater to atmospheric CO2 levels (i.e. to a pCO(2) of similar to 416 mu atm) during addition. This would allow for more TA to be added in seawater without inducing CaCO3 precipitation, using OAE at its CO2 removal potential.

Automated summary

Ocean alkalinity enhancement is a method to remove CO2 from the atmosphere and counteract ocean acidification by dissolving alkaline minerals. The dissolution of minerals suitable for this method and the occurrence of secondary precipitation of CaCO3 are critical knowledge gaps. The study found that the dissolution of certain minerals in seawater can lead to secondary CaCO3 precipitation, but this can be avoided by dilution and other methods.