4.6 Article

Tuning the selectivity in iridium-catalyzed acceptorless dehydrogenative coupling of primary alcohols

Related references

Note: Only part of the references are listed.
Article Chemistry, Applied

Recent advances on N-heterocyclic carbene transition metal complexes for dehydrogenative catalysis using alcohols

Ming Huang et al.

Summary: N-heterocyclic carbenes (NHCs) are green and versatile ligands for transition metal (TM) catalysts. NHC-TM complexes based on noble metals Ir, Ru, and Os are widely studied, while NHC-based non-noble metals catalysts are still in the early stages for sustainable dehydrogenative catalysis using alcohols.

CATALYSIS TODAY (2021)

Article Chemistry, Applied

Ir(NHC)-Catalyzed Synthesis of β-Alkylated Alcohols via Borrowing Hydrogen Strategy: Influence of Bimetallic Structure

Kihyuk Sung et al.

Summary: Various N-heterocyclic carbene-modified iridium catalysts were utilized in different alcohol reactions, including beta-alkylation, Guerbet reaction, cross-coupling, and cyclization. Mechanistic studies, such as kinetic experiments, mass analysis, and DFT calculation, were employed to explain the enhanced reactivity of bimetallic catalysts and monometallic catalysts during the reactions.

ADVANCED SYNTHESIS & CATALYSIS (2021)

Article Chemistry, Organic

Synthesis of α-Alkylated Ketones via Selective Epoxide Opening/Alkylation Reactions with Primary Alcohols

Sertac Genc et al.

Summary: A new method has been reported for converting terminal epoxides and primary alcohols into alpha-alkylated ketones under borrowing hydrogen conditions using an N-heterocyclic carbene iridium(I) catalyst in the presence of oxygen, with water as a byproduct.

ORGANIC LETTERS (2021)

Article Chemistry, Multidisciplinary

Dehydrogenative alcohol coupling and one-pot cross metathesis/dehydrogenative coupling reactions of alcohols using Hoveyda-Grubbs catalysts

Halenur Ozer et al.

Summary: In this study, in situ formed ruthenium hydride species from Grubbs type catalysts were used as efficient catalysts for dehydrogenative alcohol coupling and sequential cross-metathesis/dehydrogenative coupling reactions. The selectivity of the catalysts can be tuned by using different bases to obtain different products. With the presence of a new ligand, the performance of the catalyst was significantly improved, yielding products in quantitative yields.

NEW JOURNAL OF CHEMISTRY (2021)

Article Chemistry, Organic

Cross β-alkylation of primary alcohols catalysed by DMF-stabilized iridium nanoparticles

Masaki Kobayashi et al.

Summary: A simple method utilizing DMF-stabilized iridium nanoparticles was developed for the cross beta-alkylation of linear alcohols with benzyl alcohols, showing wide substrate scope and excellent product selectivity.

ORGANIC & BIOMOLECULAR CHEMISTRY (2021)

Article Chemistry, Inorganic & Nuclear

α-Alkylation of arylacetonitriles with primary alcohols catalyzed by backbone modified N-heterocyclic carbene iridium(I) complexes

Burcu Arslan et al.

Summary: A series of backbone-modified N-heterocyclic carbene (NHC) complexes of iridium(I) have been synthesized and used as catalysts for the alpha-alkylation of arylacetonitriles. The catalytic activities of these complexes can be controlled by modifying the N-substituents and backbone of the NHC ligands, with one complex showing the highest catalytic activity. Through a borrowing hydrogen pathway, various alpha-alkylated nitriles and aminoquinolines were obtained in high yields.

DALTON TRANSACTIONS (2021)

Review Chemistry, Applied

Manganese-Catalysed Dehydrogenative Coupling - An Overview

K. R. Rohit et al.

ADVANCED SYNTHESIS & CATALYSIS (2020)

Review Chemistry, Physical

Manganese Catalyzed Acceptorless Dehydrogenative Coupling Reactions

Satyadeep Waiba et al.

CHEMCATCHEM (2020)

Article Chemistry, Organic

Cobalt-Catalyzed Acceptorless Dehydrogenation of Alcohols to Carboxylate Salts and Hydrogen

Deepak Ranjan Pradhan et al.

ORGANIC LETTERS (2020)

Article Chemistry, Organic

Iridium Complex-Catalyzed C2-Extension of Primary Alcohols with Ethanol via a Hydrogen Autotransfer Reaction

Masaki Kobayashi et al.

JOURNAL OF ORGANIC CHEMISTRY (2020)

Article Chemistry, Inorganic & Nuclear

Reinvestigating Catalytic Alcohol Dehydrogenation with an Iridium Dihydroxybipyridine Catalyst

Wenzhi Yao et al.

ORGANOMETALLICS (2020)

Article Chemistry, Multidisciplinary

Upgrading n-Butanol to Branched Alcohols over Ni/CaxMgyO

Jie Wang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Article Chemistry, Multidisciplinary

Manganese-Catalyzed Selective Upgrading of Ethanol with Methanol into Isobutanol

Yaqian Liu et al.

CHEMSUSCHEM (2019)

Article Chemistry, Organic

Iridium(I)-Catalyzed C-C and C-N Bond Formation Reactions via the Borrowing Hydrogen Strategy

Sertac Genc et al.

JOURNAL OF ORGANIC CHEMISTRY (2019)

Article Chemistry, Applied

Pd-Catalyzed Dehydrogenative Oxidation of Alcohols to Functionalized Molecules

Takamichi Mori et al.

ORGANIC PROCESS RESEARCH & DEVELOPMENT (2019)

Article Chemistry, Inorganic & Nuclear

Ruthenium Catalyzed Dehydrogenation of Alcohols and Mechanistic Study

Mahendra K. Awasthi et al.

INORGANIC CHEMISTRY (2019)

Article Chemistry, Organic

Iron-Catalyzed β-Alkylation of Alcohols

Leo Bettoni et al.

ORGANIC LETTERS (2019)

Review Chemistry, Multidisciplinary

First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands

Lukas Alig et al.

CHEMICAL REVIEWS (2019)

Article Chemistry, Multidisciplinary

Heterodinuclear zinc and magnesium catalysts for epoxide/CO2 ring opening copolymerizations

Gemma Trott et al.

CHEMICAL SCIENCE (2019)

Article Chemistry, Multidisciplinary

Aldehyde effect and ligand discovery in Ru-catalyzed dehydrogenative cross-coupling of alcohols to esters

Xiaolin Jiang et al.

CHEMICAL COMMUNICATIONS (2019)

Review Chemistry, Multidisciplinary

Acceptorless dehydrogenative coupling reactions with alcohols over heterogeneous catalysts

S. M. A. Hakim Siddiki et al.

GREEN CHEMISTRY (2018)

Article Chemistry, Organic

Iridium(I)-Catalyzed Alkylation Reactions To Form α-Alkylated Ketones

Sertac Genc et al.

JOURNAL OF ORGANIC CHEMISTRY (2018)

Article Chemistry, Organic

Cobalt-Catalyzed Acceptorless Dehydrogenative Coupling of Primary Alcohols to Esters

Keshav Paudel et al.

ORGANIC LETTERS (2018)

Article Chemistry, Physical

Catalytic Upgrading of Ethanol to n-Butanol via Manganese-Mediated Guerbet Reaction

Naveen V. Kulkarni et al.

ACS CATALYSIS (2018)

Article Chemistry, Multidisciplinary

Zinc Oxide-Catalyzed Dehydrogenation of Primary Alcohols into Carboxylic Acids

Fabrizio Monda et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

Article Chemistry, Multidisciplinary

Manganese-Catalyzed Upgrading of Ethanol into 1-Butanol

Shaomin Fu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Second sphere ligand modifications enable a recyclable catalyst for oxidant-free alcohol oxidation to carboxylates

Eric W. Dahl et al.

CHEMICAL COMMUNICATIONS (2017)

Review Chemistry, Multidisciplinary

C-Alkylation of Ketones and Related Compounds by Alcohols: Transition-Metal-Catalyzed Dehydrogenation

Fei Huang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Multidisciplinary

General Synthesis of Amino Acid Salts from Amino Alcohols and Basic Water Liberating H2

Peng Hu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Multidisciplinary

Highly Selective Formation of n-Butanol from Ethanol through the Guerbet Process: A Tandem Catalytic Approach

Sumit Chakraborty et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Review Chemistry, Multidisciplinary

Bond Activation and Catalysis by Ruthenium Pincer Complexes

Chidambaram Gunanathan et al.

CHEMICAL REVIEWS (2014)

Article Chemistry, Multidisciplinary

Efficient and Simple Approaches Towards Direct Oxidative Esterification of Alcohols

Ritwika Ray et al.

CHEMISTRY-A EUROPEAN JOURNAL (2014)

Article Chemistry, Physical

Acceptorless dehydrogenative coupling of primary alcohols to esters by heterogeneous Pt catalysts

Sondomoyee Konika Moromi et al.

CATALYSIS SCIENCE & TECHNOLOGY (2014)

Article Chemistry, Multidisciplinary

Catalytic transformation of alcohols to carboxylic acid salts and H2 using water as the oxygen atom source

Ekambaram Balaraman et al.

NATURE CHEMISTRY (2013)

Review Multidisciplinary Sciences

Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

Chidambaram Gunanathan et al.

SCIENCE (2013)

Article Chemistry, Multidisciplinary

General and Selective Palladium-Catalyzed Oxidative Esterification of Alcohols

Saravanan Gowrisankar et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Review Chemistry, Applied

Borrowing hydrogen in the activation of alcohols

Malai Haniti S. A. Hamid et al.

ADVANCED SYNTHESIS & CATALYSIS (2007)

Article Chemistry, Organic

Oxidative dimerization of primary alcohols to esters catalyzed by iridium complexes

Aki Izumi et al.

TETRAHEDRON LETTERS (2006)

Article Chemistry, Organic

Guerbet reaction of primary alcohols leading to β-alkylated dimer alcohols catalyzed by iridium complexes

Toyomi Matsu-ura et al.

JOURNAL OF ORGANIC CHEMISTRY (2006)

Article Chemistry, Multidisciplinary

Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes

J Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)