4.6 Article

Lignin-derived porous graphene for wearable and ultrasensitive strain sensors

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 10, Issue 32, Pages 11730-11738

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2tc00953f

Keywords

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Funding

  1. National Science Foundation [1933861]
  2. Directorate For Engineering
  3. Div Of Chem, Bioeng, Env, & Transp Sys [1933861] Funding Source: National Science Foundation

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This study explores lignin as a precursor for the synthesis of laser induced graphene (LIG) and fabricates ultrasensitive strain sensors. The resulting LIG shows high sensitivity to small deformations caused by human body motions and vibrations, with a wide working range and high stability. The lignin-derived LIG can be used for monitoring human body motions and sound-related applications.
This study aimed to explore lignin as a naturally occurring aromatic precursor for the synthesis of LIG and further fabrication of ultrasensitive strain sensors for the detection of small deformations. One-step direct laser writing (DLW) induced high quality porous graphene, so called laser induced graphene (LIG), from kraft lignin under the conditions optimized for laser power, focus distance, and lignin loading. An electrode based on the resulting LIG was facilely fabricated by transferring LIG onto an elastomeric substrate (i.e., Dragon Skin (TM)). The novel LIG transfer was facilitated by spin coating followed by water lifting, leading to the full retention of porous graphene onto the elastomeric substrate. The strain sensor was shown to be highly sensitive to small human body motions and tiny deformations caused by vibrations. It had a working range of up to 14% strain with a gauge factor of 960 and showed high stability as evidenced by repetitive signals over 10 000 cycles at 4% strain. The sensor was also successfully demonstrated for detecting human speaking, breath, seismocardiography (SCG), and movement of pulse and eye. Overall, the lignin-derived LIG can serve as excellent piezoresistive materials for wearable, stretchable, and ultrasensitive strain sensors with applications in human body motion monitoring and sound-related applications.

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