Journal
INORGANIC CHEMISTRY FRONTIERS
Volume 3, Issue 3, Pages 376-380Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5qi00252d
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Funding
- National Natural Science Foundation of China [51372242, 91122030, 21210001]
- National Key Basic Research Program of China [2014CB643802]
- Jilin Province Youth Foundation [20130522122JH]
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A Gd-based coordination polymer (CP) was synthesized solvothermally with 5-triazole isopthalic acid (H2L) and Gd3+ ion. The crystal structure of GdL showed high thermal stability up to 400 degrees C and water stability for a wide pH range (pH 2-10). It can be noted that it showed the ability to highly quench the fluorescence and had a different affinity toward ssDNA and dsDNA. The Gd-based CP was employed as an effective fluorescent sensing platform for DNA and Hg2+ ion detection with sensitivity and selectivity.
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