Journal
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
Volume 10, Issue 3, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jece.2022.107805
Keywords
Radioiodine; Diphenylacetylene; trans-Stilbene; CTFs; Friedel-Crafts alkylation; DFT calculations
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Funding
- Natural Science and Engineering Research Council (NSERC) of Canada [RGPIN-2014-04427]
- Concordia University
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A robust conjugated covalent triazine framework (CTF-DPA) with high specific surface area and accessible pores has been synthesized, showing outstanding iodine-capturing performance. The mechanism of iodine adsorption is facilitated by charge transfer from specific functional groups in CTF-DPA to iodine molecules.
A robust conjugated covalent triazine framework, CTF-DPA, has been synthesized through a facile Friedel-Crafts alkylation reaction using cyanuric chloride as the cross-linking agent and diphenylacetylene (DPA) as the backbone building block. Benefiting from its unique textural and structural features such as high specific surface area (943 m(2) g(-1)), accessible pores, and abundant pi-electrons, CTF-DPA exhibits outstanding iodine-capturing performance. It features an ultrahigh iodine vapor capture capacity of 5.12 g g(-1) at 75 degrees C and 1 bar and a remarkable iodine adsorption capacity of 667 mg g(-1) in n-hexane solution. To the best of our knowledge, these are among the highest iodine adsorption capacities reported for porous organic polymers. In contrast, an analog CTF synthesized with trans-stilbene (TS) replacing DPA instead features a slight decrease in specific surface area (919 m2 g-1) but a noticeable reduction in iodine adsorption capacities. The iodine uptake mechanism was investigated by Fourier-transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), energy-dispersive Xray spectroscopy (EDX), and Raman spectroscopy as well as computationally. Density-functional theory (DFT) calculations reveal that charge transfer from conjugated C - C, phenyl, and triazine moieties to iodine molecules facilitates the generation of charged (poly)iodide species (e.g., I-3 ), enhancing the adsorption affinity/capacity. Moreover, CTF-DPA could be recycled five times while preserving above 87.6% of its initial iodine uptake capacity.
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