Journal
DALTON TRANSACTIONS
Volume 51, Issue 33, Pages 12704-12708Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt02241a
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Funding
- University of Queensland (UQ)
- Australian Research Council [DP130103157, FT140100273, FT140100986]
- Basrah Oil Company PhD scholarship
- Australian Research Council [FT140100273, FT140100986] Funding Source: Australian Research Council
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The outcomes of self-assembly reactions are influenced by the interplay of multiple factors. Here, utilizing an acetylene-appended quaterpyridine ligand, it is demonstrated that the size of the metal ion and steric repulsion between the acetylene groups exclusively lead to the formation of [M2L3] helicates instead of a helicate/tetrahedron equilibrium.
The interplay of many factors influences the outcomes of self-assembly reactions. Using an acetylene-appended quaterpyridine ligand we show that both the size of the metal ion and the presence of steric repulsion between the acetylene groups result in the exclusive formation of [M2L3] helicates rather than a helicate/tetrahedron equilibrium.
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